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VUV emission of Er3+ and Tm3 + in fluoride crystals

Identifieur interne : 002809 ( Main/Exploration ); précédent : 002808; suivant : 002810

VUV emission of Er3+ and Tm3 + in fluoride crystals

Auteurs : J. Becker [Allemagne] ; J. Yu. Gesland [France] ; N. Yu. Kirikova [Russie] ; J. C. Krupa [France] ; V. N. Makhov [Russie] ; M. Runne [Allemagne] ; M. Queffelec [France] ; T. V. Uvarova [Russie] ; G. Zimmerer [Allemagne]

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RBID : Pascal:98-0215850

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English descriptors

Abstract

VUV emission of several fluoride crystals doped with Er3+ and Tm3+ has been studied under pulsed synchrotron radiation excitation. It was shown that emission spectra of these ions in the 150-190 nm spectral range consist of both fast emission bands (decay constant in the range from a few to tens of nanoseconds) and slow ones (decay constant in the microsecond range). A model is proposed which explains the co-existence of the slow and fast components by the competition of the parity-allowed interconfiguration 4fn-15d → 4fn radiative transitions (fast emission) and parity-forbidden intraconfiguration 4fn → 4fn transitions (slow emission). Depending on the relative position of corresponding emitting levels both fast and slow emissions, or only slow, or only fast emission are observed.


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Le document en format XML

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<analytic>
<title xml:lang="en" level="a">VUV emission of Er
<sup>3+</sup>
and Tm
<sup>3</sup>
<sup>+</sup>
in fluoride crystals</title>
<author>
<name sortKey="Becker, J" sort="Becker, J" uniqKey="Becker J" first="J." last="Becker">J. Becker</name>
<affiliation wicri:level="1">
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<s1>II.Institut fur Experimentalphysik der Universitat Hamburg</s1>
<s2>22761 Hamburg</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>9 aut.</sZ>
</inist:fA14>
<country>Allemagne</country>
<wicri:noRegion>22761 Hamburg</wicri:noRegion>
<placeName>
<settlement type="city">Hambourg</settlement>
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</author>
<author>
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<country>France</country>
<placeName>
<region type="region">Pays de la Loire</region>
<region type="old region">Pays de la Loire</region>
<settlement type="city">Le Mans</settlement>
<settlement type="city">Le Mans</settlement>
</placeName>
<orgName type="university">Université du Maine</orgName>
</affiliation>
</author>
<author>
<name sortKey="Kirikova, N Yu" sort="Kirikova, N Yu" uniqKey="Kirikova N" first="N. Yu." last="Kirikova">N. Yu. Kirikova</name>
<affiliation wicri:level="1">
<inist:fA14 i1="03">
<s1>Lebedev Physical Institute</s1>
<s2>Moscow 117924</s2>
<s3>RUS</s3>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Russie</country>
<placeName>
<settlement type="city">Moscou</settlement>
<region>District fédéral central</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Krupa, J C" sort="Krupa, J C" uniqKey="Krupa J" first="J. C." last="Krupa">J. C. Krupa</name>
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</author>
<author>
<name sortKey="Runne, M" sort="Runne, M" uniqKey="Runne M" first="M." last="Runne">M. Runne</name>
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<s1>II.Institut fur Experimentalphysik der Universitat Hamburg</s1>
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</inist:fA14>
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<name sortKey="Queffelec, M" sort="Queffelec, M" uniqKey="Queffelec M" first="M." last="Queffelec">M. Queffelec</name>
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<s1>Institut de Physique Nucleaire</s1>
<s2>91406 Orsay</s2>
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<wicri:noRegion>Institut de Physique Nucleaire</wicri:noRegion>
<wicri:noRegion>Institut de Physique Nucleaire</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Uvarova, T V" sort="Uvarova, T V" uniqKey="Uvarova T" first="T. V." last="Uvarova">T. V. Uvarova</name>
<affiliation wicri:level="1">
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<country>Russie</country>
<placeName>
<settlement type="city">Moscou</settlement>
<region>District fédéral central</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Zimmerer, G" sort="Zimmerer, G" uniqKey="Zimmerer G" first="G." last="Zimmerer">G. Zimmerer</name>
<affiliation wicri:level="1">
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<s2>22761 Hamburg</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>9 aut.</sZ>
</inist:fA14>
<country>Allemagne</country>
<wicri:noRegion>22761 Hamburg</wicri:noRegion>
<placeName>
<settlement type="city">Hambourg</settlement>
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</placeName>
</affiliation>
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<series>
<title level="j" type="main">Journal of luminescence</title>
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<imprint>
<date when="1998">1998</date>
</imprint>
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</seriesStmt>
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<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Doped materials</term>
<term>Erbium additions</term>
<term>Experimental study</term>
<term>Fluorides</term>
<term>Luminescence decay</term>
<term>Photoluminescence</term>
<term>Radiative transition</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>Addition erbium</term>
<term>Addition thulium</term>
<term>Photoluminescence</term>
<term>Déclin luminescence</term>
<term>Matériau dopé</term>
<term>Transition radiative</term>
<term>Fluorure</term>
<term>7855F</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">VUV emission of several fluoride crystals doped with Er
<sup>3+</sup>
and Tm
<sup>3+</sup>
has been studied under pulsed synchrotron radiation excitation. It was shown that emission spectra of these ions in the 150-190 nm spectral range consist of both fast emission bands (decay constant in the range from a few to tens of nanoseconds) and slow ones (decay constant in the microsecond range). A model is proposed which explains the co-existence of the slow and fast components by the competition of the parity-allowed interconfiguration 4f
<sup>n-1</sup>
5d → 4f
<sup>n</sup>
radiative transitions (fast emission) and parity-forbidden intraconfiguration 4f
<sup>n</sup>
→ 4f
<sup>n</sup>
transitions (slow emission). Depending on the relative position of corresponding emitting levels both fast and slow emissions, or only slow, or only fast emission are observed.</div>
</front>
</TEI>
<affiliations>
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<li>France</li>
<li>Russie</li>
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<name sortKey="Runne, M" sort="Runne, M" uniqKey="Runne M" first="M." last="Runne">M. Runne</name>
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<name sortKey="Gesland, J Yu" sort="Gesland, J Yu" uniqKey="Gesland J" first="J. Yu." last="Gesland">J. Yu. Gesland</name>
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<name sortKey="Krupa, J C" sort="Krupa, J C" uniqKey="Krupa J" first="J. C." last="Krupa">J. C. Krupa</name>
<name sortKey="Queffelec, M" sort="Queffelec, M" uniqKey="Queffelec M" first="M." last="Queffelec">M. Queffelec</name>
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<region name="District fédéral central">
<name sortKey="Kirikova, N Yu" sort="Kirikova, N Yu" uniqKey="Kirikova N" first="N. Yu." last="Kirikova">N. Yu. Kirikova</name>
</region>
<name sortKey="Makhov, V N" sort="Makhov, V N" uniqKey="Makhov V" first="V. N." last="Makhov">V. N. Makhov</name>
<name sortKey="Uvarova, T V" sort="Uvarova, T V" uniqKey="Uvarova T" first="T. V." last="Uvarova">T. V. Uvarova</name>
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</record>

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